Difference Between EMF and Potential Difference
| Aspect | Electromotive Force (EMF) | Potential Difference (PD) | 
|---|---|---|
| Definition | The total energy supplied by a source per unit charge to drive the charge around a complete circuit. | The energy difference per unit charge between two points in a circuit. | 
| Symbol | ε | V | 
| Formula | ε= | V=W/Q | 
| Source | Produced by a cell, battery, or generator. | Occurs across circuit components (e.g., resistor, capacitor). | 
| Cause | Due to chemical, mechanical, or magnetic energy conversion. | Due to charge movement in a circuit. | 
| Circuit Condition | Present even when no current flows (open circuit). | Exists only when current flows. | 
| Unit | Volt (V) | Volt (V) | 
Definition of Electromotive Force (EMF)
Electromotive Force (EMF, denoted as ε) is the energy supplied by a source per unit charge to move it around a complete circuit. It is the driving force that pushes electrons and establishes an electric current.
Mathematically:
ε=W/Q
where:
- ε = EMF (in volts, V)
 - W = Work done or energy supplied (in joules, J)
 - Q = Charge (in coulombs, C)
 
Is EMF Really a Force?
No, EMF is not a force in the mechanical sense.
- Despite its name, EMF is not a physical force but rather a potential energy per unit charge.
 - It is called “force” because it acts as a driving agent for electric charge movement.
 - The term originated historically when scientists initially thought it was a force.
 
In summary, EMF is a voltage that drives electric current, and it is different from potential difference because it is the total energy supplied by a source, while PD refers to energy lost or used within a circuit.