Covalent bonds occur when atoms share electrons to achieve a stable electron configuration. The number of shared electron pairs between atoms determines whether the bond is single, double, or triple. Let’s break these down:
-
Single Covalent Bond: A single covalent bond is formed when two atoms share one pair of electrons. This is the most basic type of covalent bond.
-
Example: The hydrogen molecule (H₂) is formed when two hydrogen atoms share one electron each. This sharing allows both hydrogen atoms to achieve the stable configuration of two electrons in their outer shell, fulfilling the duplet rule.
-
Structure: H : H
-
-
Double Covalent Bond: A double bond occurs when two atoms share two pairs of electrons. This bond is stronger and shorter than a single bond.
-
Example: The oxygen molecule (O₂) forms a double bond when two oxygen atoms share two pairs of electrons. Each oxygen atom originally has six valence electrons and needs two more to complete its octet. By sharing two pairs of electrons, both atoms achieve a stable configuration with 8 electrons in their outer shells.
-
Structure: O = O
-
-
Triple Covalent Bond: A triple bond occurs when two atoms share three pairs of electrons. This bond is even stronger and shorter than a double bond.
-
Example: The nitrogen molecule (N₂) forms a triple bond between two nitrogen atoms. Each nitrogen atom has five valence electrons, needing three more electrons to complete their octet. By sharing three pairs of electrons, both nitrogen atoms achieve a stable electron configuration.
-
Structure: N ≡ N
-
In general, as more electron pairs are shared, the bond strength increases, and the bond length decreases. Triple bonds are the shortest and strongest, while single bonds are the longest and weakest.