(a) Li, Na, K
Order: K < Na < Li.
Ionization energy decreases as you move down the group because atomic size increases, and the outermost electron is farther from the nucleus, experiencing less attraction.
(b) Cl, Br, I
Order: I < Br < Cl.
Ionization energy decreases as you go down the group because the atomic size increases, and the outermost electron is further from the nucleus.